What is the ionic product of water?
Even pure water slightly splits into H⁺ and OH⁻. K_w is the product of their concentrations, fixed at about 10⁻¹⁴ at 25°C, locking the two ions together.
// chemistry › Acids & Bases
Calculate K_w = [H⁺][OH⁻] (=10⁻¹⁴ at 25°C), with symbol legend and real-world examples.
Kw = [H^+][OH^-] = 10⁻¹⁴
Even pure water slightly splits into H⁺ and OH⁻. K_w is the product of their concentrations, fixed at about 10⁻¹⁴ at 25°C, locking the two ions together.
Knowing one ion gives the other, since the product is fixed. It underlies the whole pH scale and links acidity to basicity.
In pure water H⁺ = OH⁻, and since their product is 10⁻¹⁴ each is 10⁻⁷, giving pH 7 - the natural midpoint.
Yes - water ionises more when warm, so K_w rises and neutral pH dips slightly below 7 in hot water. The '7 = neutral' rule is for 25°C.
[H⁺] = 10⁻⁷ and [OH⁻] = 10⁻⁷ multiply to 10⁻¹⁴ - exactly the value for neutral water.